1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides 


Vol. 62,  No. 5, pp. 372-376, Oct.  2018
10.5012/jkcs.2018.62.5.372


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  Abstract

A 1D-coordination polymer of 1D-{Cu(μ-picolinato)2}{Hakimi, 2012 #73}n (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and CuCl2 or CuBr2. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - 1D-{Cu(μ-picolinato)2}n (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a CuN2O4 environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

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  Cite this article

[IEEE Style]

Z. Mardani, V. Golsanamlou, Z. Jabbarzadeh, K. Moeini, C. C. Warren, A. M. Z. Slawin, J. D. Woollins, "1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides," Journal of the Korean Chemical Society, vol. 62, no. 5, pp. 372-376, 2018. DOI: 10.5012/jkcs.2018.62.5.372.

[ACM Style]

Zahra Mardani, Vali Golsanamlou, Zahra Jabbarzadeh, Keyvan Moeini, Cameron Carpenter Warren, Alexandra M Z Slawin, and J Derek Woollins. 2018. 1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides. Journal of the Korean Chemical Society, 62, 5, (2018), 372-376. DOI: 10.5012/jkcs.2018.62.5.372.

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ISSN(Print) 1017-2548
ISSN(Online) 2234-8530