Natural Occurring Substances as Corrosion Inhibitors for Tin in 


Vol. 53,  No. 5, pp. 485-490, Oct.  2009
10.5012/jkcs.2009.53.5.485


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  Abstract

0.1 M 중탄산소듐 용액에서 납전극부식에 대한 로소니아, 감초뿌리 및 카로브 추출물수용액의 부식방지작용에 대한것을 정전류극성방법을 사용해 연구하였다. 이들 물질들의 부식방지작용을 지적해주는 것으로 이들 물질들이 존재할 때 부식속도가 감소하는 것이 발견되었다. 부식방지효율은 추출 물농도가 증가하면 증가한다. 이들 추출물의 부식방지작용은 납표면에 이들 추출물이 흡착되어 물질 및 하전이동의 장벽을 만들어 나타내는 것으로 설명되었다. 이들 추출물의 납표면에 흡착은 자발적으로 일어나며, Freundlich 등온흡착을 따르는 것으로 발견되었다. 또한, 변전위양극분극법을 사용해 이들 추출물은 염소를 포함한 용액에서 납의 움푹패이게 하는 부식으로부터 잘 보호해주는 것이 발견되었다. The inhibitive action of the aqueous extract of lawsonia, licorice root and carob toward the corrosion of tin electrode in 0.1 M NaHC3 solutions was investigated using galvanostatic polarization measurements. It was found that the corrosion rate decreases in the presence of these extracts indicating the inhibiting of these compounds. The inhibition efficiency increases with increasing extract concentration. The inhibition action of these extracts was explained in view of adsorption of its compounds onto the tin surface, making a barrier to mass and charge transfer. The adsorption of these extracts on the tin surface was found to be a spontaneous process and follow Freundlich adsorption isotherm. It is also found that these extracts provide a good protection to tin against pitting corrosion in chloride containing solution using potentiodynamic anodic polarization technique.

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  Cite this article

[IEEE Style]

, "Natural Occurring Substances as Corrosion Inhibitors for Tin in," Journal of the Korean Chemical Society, vol. 53, no. 5, pp. 485-490, 2009. DOI: 10.5012/jkcs.2009.53.5.485.

[ACM Style]

. 2009. Natural Occurring Substances as Corrosion Inhibitors for Tin in. Journal of the Korean Chemical Society, 53, 5, (2009), 485-490. DOI: 10.5012/jkcs.2009.53.5.485.

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