Synthesis and Spectroscopic Studies of Metal Complexes Formed in the Reaction of Metal Ions with Urea at High Temperature 


Vol. 51,  No. 4, pp. 339-345, Aug.  2007
10.5012/jkcs.2007.51.4.339


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  Abstract

Urea는 높은 온도(60~80 °C)의 수용액 상태에서 PtC2, 2[PtC6]·62O, 2[IrC6] Ni(C3C22 와 반응해서 각각 (1)[PtC2(Urea)]·22O, (2)(N42[PtC6], (3)(N42[IrC6]·2O, (4)[N2(OH2(NCO2(2O2]의 complexes를 생성 한다. complexe 1에서 urea는 중성 bidentate 리간드로써 Pt(II)와 배위한다. complexe 2,3,4에서는 높은 온도에서 반 응하는 동안 배위 urea분자들이 분해되고 다양한 반응생성물들을 얻을 수 있다. 모든 complexes은 각각 적당한 수득률 로 dark green(1) yellow(2), pale brown (3) faint green(4)의 침전물로 분리된다. 반응생성물은 열분석, IR, 1H and 13C NMR spectra에 의해 측정 되었다. 이 complexes의 구성을 설명하는 일반적인 매카니즘이 제시되었다. Urea reacts with PtC2, 2[PtC6]·62O, 2[IrC6] and Ni(C3C22 in aqueous solution at high temperature (60-80 °C) yielding [PtC2(Urea)]·22O (1), (N42[PtC6] (2), (N42[IrC6]·2O (3) and [N2(OH2(NCO2(2O2] (4) complexes, respectively. In complex 1, urea coordinates to Pt(II) as a neutral bidentate ligand via amido nitrogen atoms. In complexes 2, 3 and 4 it seems that the coordinated urea molecules decompose during the reaction at high temperature and a variety of reaction products are obtained. All complexes were isolated in moderate yields as dark green (1), yellow (2), pale brown (3) and faint green (4) precipitates, respectively. The reaction products were characterized by their microanalysis, IR, 1H and 13C NMR spectra as well as thermal analysis. General mechanisms describing the formation of these complexes were suggested.

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  Cite this article

[IEEE Style]

A. S. Gaballa, S. M. Teleb, E. Nour, "Synthesis and Spectroscopic Studies of Metal Complexes Formed in the Reaction of Metal Ions with Urea at High Temperature," Journal of the Korean Chemical Society, vol. 51, no. 4, pp. 339-345, 2007. DOI: 10.5012/jkcs.2007.51.4.339.

[ACM Style]

Akmal S. Gaballa, Said M. Teleb, and El-Metwally Nour. 2007. Synthesis and Spectroscopic Studies of Metal Complexes Formed in the Reaction of Metal Ions with Urea at High Temperature. Journal of the Korean Chemical Society, 51, 4, (2007), 339-345. DOI: 10.5012/jkcs.2007.51.4.339.

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