Amination of Organic Azides using Tetracarbonylhydridoferrate(O) as a Reducing Agent(Ⅰ) 


Vol. 29,  No. 4, pp. 437-440, Aug.  1985


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  Abstract

유기아지드화물은 일산화탄소대기압하, 실온에서 높은 선택적 환원시약인 테트라카르 보닐철산염의 존재하에서 높은 수득율의 아민으로 환원되었다. 특히 벤조일아지드는 동일시약내 일산화탄소 대기압 실온에서는 에틸페닐카바메이트를 주나, -40℃에서는 정량적으로 벤즈아미드가 얻어졌다. Organic azides were reduced to organic amines in the presence of tetracarbonylhydridoferrate(O) as a highly selective reducing agent at room temperature under carbon monoxide atmosphere. Particularly, benzoylazide gave ethylphenylcarbamate at room temperature but gave benzamide quantitatively at -40℃ in the presence of tetracarbonylhydridoferrate under carbon monoxide atmosphere.

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  Cite this article

[IEEE Style]

S. C. Shim and K. N. Choi, "Amination of Organic Azides using Tetracarbonylhydridoferrate(O) as a Reducing Agent(Ⅰ)," Journal of the Korean Chemical Society, vol. 29, no. 4, pp. 437-440, 1985. DOI: .

[ACM Style]

Sang Chul Shim and Kui Nam Choi. 1985. Amination of Organic Azides using Tetracarbonylhydridoferrate(O) as a Reducing Agent(Ⅰ). Journal of the Korean Chemical Society, 29, 4, (1985), 437-440. DOI: .

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ISSN(Online) 2234-8530